河北工业大学应用物理系;中国联合网络通信有限公司河北省分公司;
ZnO因具有良好的光学活性、无毒和化学稳定性而被广泛应用于光催化领域,但单一的ZnO作为光催化剂时还存在一些缺点,如光生电子-空穴(e~--h~+)复合快、对可见光利用率低和生成活性氧物种少等.为提高ZnO的光催化性能,研究人员采用多种方法对ZnO进行改性.总结了近几年ZnO光催化剂的改性手段,其中主要包括元素掺杂、形貌修饰和半导体复合,并简要阐述了ZnO复合材料的催化机理,为进一步提升ZnO的光催化性能及应用提供了参考.
691 | 0 | 28 |
下载次数 | 被引频次 | 阅读次数 |
[1] RUAN W,HU J,QI J,et al.Removal of Dyes from Wastewater by Nanomaterials:A Review[J].Advanced Materials Letters,2019,10(1):9-20.doi:10.5185/amlett.2019.2148
[2] NIDHEESH P V,GANDHIMATHI R,RAMESH S T.Degradation of Dyes from Aqueous Solution by Fenton Processes:A Review[J].Environmental Science and Pollution Research,2013,20(4):2099-2132.doi:10.1007/s11356-012-1385-z
[3] KHAMPARIA S,JASPAL D K.Adsorption in Combination with Ozonation for the Treatment of Textile Waste Water:A Critical Review[J].Frontiers of Environmental Science & Engineering,2017,11(1):1-18.doi:10.1007/s11783-017-0899-5
[4] YANG W,ZHOU H,CICEK N.Treatment of Organic Micropollutants in Water and Wastewater by UV-based Processes:A Literature Review[J].Critical Reviews in Environmental Science and Technology,2014,44(13):1443-1476.doi:10.1080/10643389.2013.790745
[5] CHAN S H S,WU T Y,JUAN J C,et al.Recent Developments of Metal Oxide Semiconductors as Photocatalysts in Advanced Oxidation Processes(AOPs) for Treatment of Dye Waste-water[J].Journal of Chemical Technology and Biotechnology,2011,86(9):1130-1158.doi:10.1002/jctb.2636
[6] EREN Z.Ultrasound as a Basic and Auxiliary Process for Dye Remediation:A Review[J].Journal of Environmental Management,2012,104:127-141.doi:10.1016/j.jenvman.2012.03.028
[7] QIU P,PARK B,CHOI J,et al.A Review on Heterogeneous Sonocatalyst for Treatment of Organic Pollutants in Aqueous Phase Based on Catalytic Mechanism[J].Ultrasonics Sonochemistry,2018,45:29-49.doi:10.1016/j.ultsonch.2018.03.003
[8] GAUTAM S,AGRAWAL H,THAKUR M,et al.Metal Oxides and Metal Organic Frameworks for the Photocatalytic Degradation:A Review[J].Journal of Environmental Chemical Engineering,2020,8:103726.doi:10.1016/j.jece.2020.103726
[9] KARTHIKEYAN C,ARUNACHALAM P,RAMACHANDRAN K,et al.Recent Advances in Semiconductor Metal Oxides with Enhanced Methods for Solar Photocatalytic Applications[J].Journal of Alloys and Compounds,2020,828:154281.doi:10.1016/j.jallcom.2020.154281
[10] GANESH V,SALEM G F,YACHIA I S,et al.Synthesis,Optical and Photoluminescence Properties of Cu-doped ZnO Nano-fibers Thin Films:Nonlinear Optics[J].Journal of Electronic Materials,2018,47:1798-1805.doi:10.1007/s11664-017-5950-6
[11] DANESHVAR N,SALARI D,KHATAEE A R.Photocatalytic Degradation of AZO Dye Acid Red 14 in Water on ZnO as an Alternative Catalyst to TiO2[J].Journal of Photochemistry and Photobiology A:Chemistry,2004,162:317-322.doi:10.1016/s1010-6030(03)00378-2
[12] LEE K M,LAI C W,NGAI K S,et al.Recent Developments of Zinc Oxide Based Photocatalyst in Water Treatment Technology:A Review[J].Water Research,2016,88:428-448.doi:10.1016/j.watres.2015.09.045
[13] PRABAKARAN E,PILLAY K.Synthesis of N-doped ZnO Nanoparticles with Cabbage Morphology as a Catalyst for the Efficient Photocatalytic Degradation of Methylene Blue Under UV and Visible Light[J].RSC Advances,2019,9:7509-7535.doi:10.1039/c8ra09962f
[14] SCHMIDT-MENDE L,MACMANUS-DRISCOLL J L.ZnO-nanostructures,Defects,and Devices[J].Materials Today,2007,10(5):40-48.doi:10.1016/s1369-7021(07)70078-0
[15] CURRI M,COMPARELLI R,COZZOLI P,et al.Colloidal Oxide Nanoparticles for the Photocatalytic Degradation of Organic Dye[J].Biomaterials Advances,2003,23(1/2):285-289.doi:10.1016/s0928-4931(02)00250-3
[16] BHAPKAR A R,BHAME S.A Review on ZnO and Its Modifications for Photocatalytic Degradation of Prominent Textile Effluents:Synthesis,Mechanisms,and Future Directions[J].Journal of Environmental Chemical Engineering,2024,12(3):112553.doi:10.1016/j.jece.2024.112553
[17] ABDULLAH F H,BAKAR N H H A,BAKAR M A.Current Advancements on the Fabrication,Modification,and Industrial Application of Zinc Oxide as Photocatalyst in the Removal of Organic and Inorganic Contaminants in Aquatic Systems[J].Journal of Hazardous Materials,2021,424:127416.doi:10.1016/j.jhazmat.2021.127416
[18] PRADEEV-RAJ K,SADAIYANDI K,KENNEDY A,et al.Influence of Mg Doping on ZnO Nanoparticles for Enhanced Photocatalytic Evaluation and Antibacterial Analysis[J].Nanoscale Research Letters,2018,13:229.doi:10.1186/s11671-018-2643-x
[19] ABRI R A,MARZOUQI F A,KUVAREGA A T,et al.Nanostructured Cerium-doped ZnO for Photocatalytic Degradation of Pharmaceuticals in Aqueous Solution[J].Journal of Photochemistry and Photobiology A:Chemistry,2019,384:112065.doi:10.1016/j.jphotochem.2019.112065
[20] AJALA F,HAMROUNI A,HOUAS A,et al.The Influence of Al Doping on the Photocatalytic Activity of Nanostructured ZnO:The Role of Adsorbed Water[J].Applied Surface Science,2018,445:376-382.doi:10.1016/j.apsusc.2018.03.141
[21] ADAM R E,ALNOOR H,POZINA G,et al.Synthesis of Mg-doped ZnO NPs via a Chemical Low-temperature Method and Investigation of the Efficient Photocatalytic Activity for the Degradation of Dyes Under Solar Light[J].Solid State Sciences,2020,99:106053.doi:10.1016/j.molliq.2020.113633
[22] AGALE P,SALVE V,MARDIKAR S,et al.Synthesis and Characterization of Hierarchical Sr-doped ZnO Hexagonal Nanodisks as an Efficient Photocatalyst for the Degradation of Methylene Blue Dye Under Sunlight Irradiation[J].Applied Surface Science,2024,672:160795.doi:10.1016/j.apsusc.2024.160795
[23] SHIRDEL B,BEHNAJADY M A.Visible-light-induced Degradation of Rhodamine B by Ba Doped ZnO Nanoparticles[J].Journal of Molecular Liquids,2020,315:113633.doi:10.1016/j.molliq.2020.113633
[24] THIRUMOOLAN D,RAGUPATHY S,RENUKADEVI S,et al.Influence of Nickel Doping and Cotton Stalk Activated Carbon Loading on Structural,Optical,and Photocatalytic Properties of Zinc Oxide Nanoparticles[J].Journal of Photochemistry and Photobiology A-chemistry,2024,448:115300.doi:10.1016/j.molliq.2020.113633
[25] BASHIR M,BATOOL M,ARIF N,et al.Strontium-based Nanomaterials for the Removal of Organic/inorganic Contaminants from Water:A Review[J].Coordination Chemistry Reviews,2023,492:215286.doi:10.1016/j.ccr.2023.215286
[26] SELVARAJ S,PALANIVEL B,PATRICK S,et al.Effect of Sr Doping in ZnO Microspheres for Solar Light-driven Photodegradation of Organic Pollutants[J].Journal of Materials Science:Materials in Electronics,2022,33:8777-8788.doi:10.1007/s10854-021-06875-6
[27] BHOSALE A,KADAM J,GADE T K,et al.Efficient Photodegradation of Methyl Orange and Bactericidal Activity of Ag Doped ZnO Nanoparticles[J].Journal of the Indian Chemical Society,2023,100(2):100920.doi:10.1016/j.jics.2023.100920
[28] MOHAMMADZADEH K R,TAYEBEE R,AHASANI F.New and Highly Efficient Ag Doped ZnO Visible Nano Photocatalyst for Removing of Methylene Blue[J].Journal of Materials Science:Materials in Electronics,2017,28:5941-5952.doi:10.1007/s10854-016-6268-5
[29] AHAMD M,REHMAN W,KHAN M M,et al.Phytogenic Fabrication of ZnO and Gold Decorated ZnO Nanoparticles for Photocatalytic Degradation of Rhodamine B[J].Journal of Environmental Chemical Engineering,2021,9:104725.doi:10.1016/j.jece.2020.104725
[30] DENG Q,TANG H,LIU G,et al.The Fabrication and Photocatalytic Performances of Flower-like Ag Nanoparticles/ZnO Nanosheets-assembled Microspheres[J].Applied Surface Science,2015,331:50-57.doi:10.1016/j.apsusc.2014.12.202
[31] PATHAK T K,KROON R E,SWART H C.Photocatalytic and Biological Applications of Ag and Au Doped ZnO Nanomaterial Synthesized by Combustion[J].Vacuum,2018,157:508-513.doi:10.1016/j.vacuum.2018.09.020
[32] AFTAB S,SHABIR T,SHAH A,et al.Highly Efficient Visible Light Active Doped ZnO Photocatalysts for the Treatment of Wastewater Contaminated with Dyes and Pathogens of Emerging Concern[J].Nanomaterials,2022,12(3):486.doi:10.3390/nano12030486
[33] di VALENTIN C,PACCHIONI G.Trends in Non-metal Doping of Anatase TiO2:B,C,N and F[J].Catalysis Today,2013,206:12-18.doi:10.1016/j.cattod.2011.11.030
[34] WANG Y,GE S,CHENG W,et al.Microwave Hydrothermally Synthesized Metal-organic Framework-5 Derived C-doped ZnO with Enhanced Photocatalytic Degradation of Rhodamine B[J].Langmuir,2020,36:9658-9667.doi:10.1021/acs.langmuir.0c00395
[35] ZHANG Y,ZHOU J,CHEN X,et al.MOF-derived C-doped ZnO Composites for Enhanced Photocatalytic Performance Under Visible Light[J].Journal of Alloys and Compounds,2019,777:109-118.doi:10.1016/j.jallcom.2018.10.383
[36] VELUMANI M,RAJAMOHAN S,PANDEY A,et al.Nanocomposite from Tannery Sludge-derived Biochar and Zinc Oxide Nanoparticles for Photocatalytic Degradation of Bisphenol a Toward Dual Environmental Benefits[J].Science of the Total Environment,2024,907:167896.doi:10.1016/j.scitotenv.2023.167896
[37] MANDOR H,EL-SHTOUKHY E S Z,ABDELWAHAB O,et al.A Flow-circulation Reactor for Simultaneous Photocatalytic Degradation of Ammonia and Phenol Using N-doped ZnO Beads[J].Alexandria Engineering Journal,2021,61(5):3385-3401.doi:10.1016/j.aej.2021.08.052
[38] TANG C,CHEN C,ZHANG H,et al.Enhancement of Degradation for Nitrogen Doped Zinc Oxide to Degrade Methylene Blue[J].Physica B Condensed Matter,2020,583:412029.doi:10.1016/j.physb.2020.412029
[39] MIRZAEIFARD Z,SHARIATINIA Z,JOURSHABANI M,et al.ZnO Photocatalyst Revisited:Effective Photocatalytic Degradation of Emerging Contaminants Using S-doped ZnO Nanoparticles Under Visible Light Radiation[J].Industrial & Engineering Chemistry Research,2020,59(36):15894-15911.doi:10.1021/acs.iecr.0c03192
[40] AHMAD I,AKHTAR M S,AHMED E,et al.Aluminium and Cerium Co-doped ZnO Nanoparticles:Facile and Inexpensive Synthesis and Visible Light Photocatalytic Performances[J].Journal of Rare Earths,2021,39(2):151-159.doi:10.1016/j.jre.2019.11.006
[41] REDDYA I N,REDDYA C V,SHIM J,et al.Excellent Visible-light Driven Photocatalyst of (Al,Ni)Co-doped ZnO Structures for Organic Dye Degradation[J].Catalysis Today,2020,340:277-285.doi:10.1016/j.cattod.2018.07.030
[42] NADEEM M S,MUNAWAR T,MUKHTAR F,et al.Enhancement in the Photocatalytic and Antimicrobial Properties of ZnO Nanoparticles by Structural Variations and Energy Bandgap Tuning Through Fe and Co Co-doping[J].Ceramics International,2020,47(8):11109-11121.doi:10.1016/j.ceramint.2020.12.234
[43] DHANRAJ C,RAVICHANDRAN K,KAVITHA P,et al.Excess Free-electrons Activated Photocatalytic Ability of ZnO Films Through Co-doping of Higher Oxidation State Transition Metals Ta and Mo[J].Inorganic Chemistry Communications,2020,118:107986.doi:10.1016/j.inoche.2020.107986
[44] BOURFAA F,BOUTELALA A,AIDA M S,et al.Influence of Seed Layer Surface Position on Morphology and Photocatalysis Efficiency of ZnO Nanorods and Nanoflowers[J].Journal of Nanomaterials,2020,2020:4072351-4072359.doi:10.1155/2020/4072351
[45] SON S,JUNG P H,PARK J,et al.Customizable 3D-printed Architecture with ZnO-based Hierarchical Structures for Enhanced Photocatalytic Performance[J].Nanoscale,2018,10(46):21696-21702.doi:10.1039/c8nr06788k
[46] SHENDE P,KASTURE P,GAUD R.Nanoflowers:The Future Trend of Nanotechnology for Multi-applications[J].Artificial Cells,Nanomedicine,and Biotechnology,2018,46:413-422.doi:10.1080/21691401.2018.1428812
[47] HUANG N,SHU J,WANG Z,et al.One-step Pyrolytic Synthesis of ZnO Nanorods with Enhanced Photocatalytic Activity and High Photostability Under Visible Light and UV Light Irradiation[J].Journal of Alloys and Compounds,2015,648:919-929.doi:10.1016/j.jallcom.2015.07.039
[48] LEELAVATHI A,MADRAS G,RAVISHANKAR N.Origin of Enhanced Photocatalytic Activity and Photoconduction in High Aspect Ratio ZnO Nanorods[J].Physical Chemistry Chemical Physics,2013,15(26):10795-10802.doi:10.1039/c3cp51058a
[49] HAN Z,LIAO L,WU Y,et al.Synthesis and Photocatalytic Application of Oriented Hierarchical ZnO Flower-rod Architectures[J].Journal of Hazardous Materials,2012,217:100-106.doi:10.1016/j.jhazmat.2012.02.074
[50] AULAKH M K,KAUR S,PAL B,et al.Morphological Influence of ZnO Nanostructures and Their Cu Loaded Composites for Effective Photodegradation of Methyl Parathion[J].Solid State Sciences,2020,99:106045.doi:10.1016/j.solidstatesciences.2019.106045
[51] AMEEN F,DAWOUD T,ALNADHARI S.Ecofriendly and Low-cost Synthesis of ZnO Nanoparticles from Acremonium Potronii for the Photocatalytic Degradation of AZO Dyes[J].Environmental Research,2021,202(2):111700.doi:10.1016/j.envres.2021.111700
[52] BAILLARD A,APPERT E,RAPENNE L,et al.Significance of the Different Exposed Surfaces of ZnO Single Crystals and Nanowires on the Photocatalytic Activity and Processes[J].Small Structures,2024,5:2300540.doi:10.1002/sstr.202300540
[53] MOHAMED K M,BENITTO J J,VIJAYA J J,et al.Recent Advances in ZnO-based Nanostructures for the Photocatalytic Degradation of Hazardous,Non-biodegradable Medicines[J].Crystals,2023,13(2):13020329.doi:10.3390/cryst13020329
[54] PAN J,DONG Z,WANG B,et al.The Enhancement of Photocatalytic Hydrogen Production via Ti3+ Self-doping Black TiO2/g-C3N4 Hollow Core-shell Nano-heterojunction[J].Applied Catalysis B:Environment and Energy,2019,242:92-99.doi:10.1016/j.apcatb.2018.09.079
[55] HITAM C N C,JALIL A A.A Review on Exploration of Fe2O3 Photocatalyst Towards Degradation of Dyes and Organic Contaminants[J].Journal of Environmental Management,2020,258:110050.doi:10.1016/j.jenvman.2019.110050
[56] ZHANG L,JARONIEC M.Toward Designing Semiconductor-semiconductor Heterojunctions for Photocatalytic Applications[J].Applied Surface Science,2018,430:2-17.doi:10.1016/j.apsusc.2017.07.192
[57] SHANMUGAM P,NGULLIE R C,MEEJOO-SMITH S,et al.Visible-light Induced Photocatalytic Removal of Methylene Blue Dye by Copper Oxide Decorated Zinc Oxide Nanorods[J].Materials Science for Energy Technologies,2023,6:359-367.doi:10.1016/j.mset.2023.03.001
[58] ZHANG Y,LIU B,CHEN N,et al.Synthesis of SnO2/ZnO Flowerlike Composites Photocatalyst for Enhanced Photocatalytic Degradation of Malachite Green[J].Optical Materials,2022,133:112978.doi:10.1016/j.optmat.2022.112978
[59] HASHEM E M,HAMZA M A,EL-SHAZLY A N,et al.Novel Z-scheme/type-II CdS@ZnO/g-C3N4 Ternary Nanocomposites for the Durable Photodegradation of Organics:Kinetic and Mechanistic Insights[J].Chemosphere,2021,277:128730.doi:10.1016/j.chemosphere.2020.128730
[60] TRUONG T T,PHAM T T,TRUONG T T T,et al.Synthesis,Characterization of Novel ZnO/CuO Nanoparticles,and the Applications in Photocatalytic Performance for Rhodamine B Dye Degradation[J].Environmental Science and Pollution Research,2022,29:22576-22588.doi:10.1007/s11356-021-17106-0
[61] THIRUPUGAZHMANI V,SHAMEENA S,THIRUMALAI K,et al.Ultrasonic Assisted Synthesis of RGO Supported HoVO4-ZnO Nanocomposites,Their Enhanced Photocatalytic Activities and Rhodamine B Degradation[J].Environmental Research,2022,214:113743.doi:10.1016/j.envres.2022.113743
[62] TANJI K,NAVIO J A,CHAQROUNE A,et al.Fast Photodegradation of Rhodamine B and Caffeine Using ZnO-hydroxyapatite Composites Under UV-light Illumination[J].Catalysis Today,2020,388/389:176-186.doi:10.1016/j.cattod.2020.07.044
基本信息:
DOI:10.13763/j.cnki.jhebnu.nse.202502002
中图分类号:O644.1;O643.36;X703
引用信息:
[1]段苏田,蔡丽景,贾静薇等.改性ZnO光催化降解有机污染物的研究进展[J].河北师范大学学报(自然科学版),2025,49(02):121-135.DOI:10.13763/j.cnki.jhebnu.nse.202502002.
基金信息:
国家自然科学基金(51702083,11547250); 河北省自然科学基金(A2019202190); 第三批河北省青年拔尖人才项目